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排序方式: 共有259条查询结果,搜索用时 31 毫秒
31.
A generic bubble structure in a 230 kHz ultrasonic field is observed in a partly developed standing wave field in water. It is characterized by high-speed imaging, sonoluminescence recordings, and surface cleaning tests. The structure has two distinct bubble populations. Bigger bubbles (much larger than linear resonance size) group on rings in planes parallel to the transducer surface, apparently in locations of driving pressure minima. They slowly rise in a jittering, but synchronous way, and they can have smaller satellite bubbles, thus resembling the arrays of bubbles observed by Miller [D. Miller, Stable arrays of resonant bubbles in a 1-MHz standing-wave acoustic field, J. Acoust. Soc. Am. 62 (1977) 12]. Smaller bubbles (below and near linear resonance size) show a fast "streamer" motion perpendicular to and away from the transducer surface. While the bigger bubbles do not emit light, the smaller bubbles in the streamers show sonoluminescence when they pass the planes of high driving pressure. Both bubble populations exhibit cleaning potential with respect to micro-particles attached to a glass substrate. The respective mechanisms of particle removal, though, might be different. 相似文献
32.
Griffin JL Nicholls AW Keun HC Mortishire-Smith RJ Nicholson JK Kuehn T 《The Analyst》2002,127(5):582-584
The application of a 1 mm TXI (1H/13C/15N) microlitre NMR probe with z-gradient for metabolic profiling of biofluids is described. The probe was used to provide spectral profiles for rat blood plasma using only approximately 2 microl of fluid with a range of solvent suppression techniques. Using a similar amount of fluid, spectra were obtained from rat and mouse cerebrospinal fluid, demonstrating that the probe could be used to profile rodents metabolically via biofluids previously inaccessible to NMR analysis without the need for termination. 相似文献
33.
Till Opatz 《Tetrahedron》2004,60(39):8613-8626
Carbohydrates are useful polyfunctional scaffold molecules which allow the selective attachment of a number of different side chains. The combinatorial solid phase synthesis of diverse amino acid or peptide conjugates of a polyfunctional glucose scaffold based on a set of selectively removable and orthogonally stable protecting groups is described. The resulting carbohydrate-peptide hybrids constitute potential turn mimetics. 相似文献
34.
Krivec S Buchmayr M Detzel T Froemling T Fleig J Hutter H 《Analytical and bioanalytical chemistry》2011,400(3):649-657
The action of Na+ incorporation into thin insulating films and transport therein under influence of a bias voltage and temperature (BT stress)
is the subject of this work. Deposited onto highly n-doped Si wafers, the insulators get BT stressed and subsequently investigated by means of time-of-flight–secondary ion mass
spectrometry (ToF-SIMS). A thin PMMA film, spin-coated onto the insulator, serves as host matrix for a defined amount of Na+, provided via sodium triflate. Combining BT stress and ToF-SIMS depth profiling enables the unambiguous detection of Na+, incorporated into the insulating material. The insulators of interest vary in their nitride content: SiO2, SiOxNy, and Si3N4. For SiO2, it is shown that once a threshold BT stress is exceeded, Na+ gets quantitatively incorporated from PMMA into the underlying insulator, finally accumulating at the SiO2/Si interface. A quantitative assessment by combination of Butler–Volmer kinetics with hopping dynamics reveals activation
energies of E
a = 1.55 − 2.04 eV for Na+ transport in SiO2 with varying thickness. On the other hand, SiOxNy and Si3N4 films show a different Na+ incorporation characteristic in this type of experiment, which can be explained by the higher coordination of nitrogen and
hence the reduced Na+ permeability within these insulators. 相似文献
35.
L. Till 《Journal of Thermal Analysis and Calorimetry》1971,3(2):177-180
Decomposition temperatures of barium peroxide in equilibrium with the oxygen pressure in the gas phase have been determined by thermogravimetric measurements at temperatures from 670 to 843. Enthalpies and entropies of the reaction BaO2= =BaO+0.5O2 and of the formation of BaO2 have been calculated.
Zusammenfassung Zersetzungstemperaturen von mit dem Sauerstoffdruck in der Gasphase in Gleichgewicht stehendem Bariumperoxyd wurden thermogravimetrisch im Temperaturbereich von 670 bis zu 843 ermittelt. Enthalpie- und Entropiewerte der Reaktion BaO2= =BaO+0.5 O2 und der Bildung von BaO2 wurden errechnet.
Résumé On a déterminé les températures de décomposition du peroxyde de baryum en équilibre avec la pression d'oxygène de la phase gazeuse, par mesures thermogravimétriques entre 670 et 843. On a calculé les enthalpies et les entropies correspondant à la réaction BaO2=BaO+0.5 O2 et à la formation de BaO2.
, , , 670 843. BaO2= + +0.5 O2 BaO2.相似文献
36.
G. Várhegyi M. J. Antal Jr. Piroska Szabó Emma Jakab F. Till 《Journal of Thermal Analysis and Calorimetry》1996,47(2):535-542
The complexity of the phenomena which arise during the heating of the various substances seldom can be described by a single reaction kinetic equation. As a consequence, sophisticated models with several unknown parameters have to be developed. The determination of the unknown parameters and the validation of the models requires the simultaneous evaluation of whole series of experiments. We can accept a model and its parameters if, and only if we get a reasonable fit to several experiments carried out at different experimental conditions. In the field of the thermal analysis the method of least squares alone seldom can select abest model or abest set of parameter values. Nevertheless, the careful evaluation of the experiments may help in the discerning between various chemical or physical assumptions by the quality of the corresponding fit between the experimental and the simulated date. The problem is illustrated by the thermal de-composition of cellulose under various experimental conditions.This research program was funded by the National Science Foundation (grant INT 8914934), the US Hungarian Science and Technology Joint Fund (grants 90b-22 and 93b-375), the Hungarian National Research Fund (OTKA, grant 3077/91) and the Coral Industries Endowment. 相似文献
37.
Böcking T Kilian KA Hanley T Ilyas S Gaus K Gal M Gooding JJ 《Langmuir : the ACS journal of surfaces and colloids》2005,21(23):10522-10529
Surface modification with oligo(ethylene oxide) functionalized monolayers terminated with reactive headgroups constitutes a powerful strategy to provide specific coupling of biomolecules with simultaneous protection from nonspecific adsorption on surfaces for the preparation of biorecognition interfaces. To date, oligo(ethylene oxide) functionalized monolayer-forming molecules which can be activated for attachment of biomolecules but which can selectively form monolayers onto hydrogen terminated silicon have yet to be developed. Here, self-assembled monolayers (SAMs) containing tetra(ethylene oxide) moieties protected with tert-butyl dimethylsilyl groups were formed by thermal hydrosilylation of alkenes with single-crystal Si(111)-H. The protection group was used to avoid side reactions with the hydride terminated silicon surface. Monolayer formation was carried out using solutions of the alkene in the high-boiling-point solvent 1,3,5-triethylbenzene. The protecting group was removed under very mild acidic conditions to yield a free hydroxyl functionality, a convenient surface moiety for coupling of biological entities via carbamate bond formation. The chemical composition and structure of the monolayers before and after deprotection were characterized by X-ray photoelectron spectroscopy (XPS) and X-ray reflectometry. To demonstrate the utility of this surface for covalent modification, two reagents were compared and contrasted for their ability to activate the surface hydroxyl groups for coupling of free amines, carbonyl diimidazole (CDI), and disuccinimidyl carbonate (DSC). Analysis of XP spectra before and after activation by CDI or DSC, and after subsequent reaction with glycine, provided quantitative information on the extent of activation and overall coupling efficiencies. CDI activated surfaces gave poor coupling yields under various conditions, whereas DSC mediated activation followed by aminolysis at neutral pH was found to be an efficient method for the immobilization of amines on tetra(ethylene oxide) modified surfaces. 相似文献
38.
S. T. Howard J. P. Huke I. W. Parsons S. J. Till 《International journal of quantum chemistry》1991,39(1):71-91
The usefulness of the MS -Xα method for calculating molecular transition properties is investigated in a study of NO2. Two-dimensional potential surfaces are obtained in C2v symmetry for the X?2A1/Ã2B2 system. Potential curves that approximately follow the asymmetric stretch coordinate are also presented: On investigation, no symmetry-broken solutions were found. At all nuclear geometries investigated, the muffin-tin sphere radii were chosen by an energy-minimization technique. The inclusion of corrections to the muffin-tin form of the Xα total energy is shown to be essential, if the computed surfaces are to be qualitatively correct. The transition dipole moment connecting the two states is evaluated as a function of nuclear coordinates, using the transition-state approximation. Finally, the radiative decay of a single vibronic level in NO2 is modeled and the relevance to experiment is discussed. 相似文献
39.
Dina Carbone Olivier Plantevin Raul Gago Cristian Mocuta Oier Bikondoa Alejandro Alija Lucien Petit Hamid Djazuli Till‐Hartmut Metzger 《Journal of synchrotron radiation》2008,15(4):414-419
A compact portable vacuum‐compatible chamber designed for surface X‐ray scattering measurements on beamline ID01 of the European Synchrotron Radiation Facility, Grenoble, is described. The chamber is versatile and can be used for in situ investigation of various systems, such as surfaces, nanostructures, thin films etc., using a variety of X‐ray‐based techniques such as reflectivity, grazing‐incidence small‐angle scattering and diffraction. It has been conceived for the study of morphology and structure of semiconductor surfaces during ion beam erosion, but it is also used for the study of surface oxidation or thin film growth under ultra‐high‐vacuum conditions. Coherent X‐ray beam experiments are also possible. The chamber is described in detail, and examples of its use are given. 相似文献
40.
Kerim Isik Yoshinori Yoshida Lin Chen Till Clausmeyer A. Erman Tekkaya 《Comptes Rendus Mecanique》2018,346(8):770-778
This paper presents a methodology to model a blanking process using a continuum mechanical damage model. A variant of the Lemaitre model, in which the quasi-unilateral conditions are taken into consideration to modify the damage behavior under compressive stress states, is selected as material model. S45C high-carbon steel is analyzed experimentally. To characterize the damage behavior of the material, notched round bar tensile tests with three different notch radii (6 mm, 10 mm, and 20 mm) using image analysis are performed. Using digital image processing, the strain at the deformation zone can be computed for the load–strain curves. Those curves are used as an objective function to determine the parameters of the Lemaitre damage model. The experimental results are compared with the results of the FE analysis of the tensile test. The identified model parameters are used in numerical investigations of axisymmetric blanking. The effect of the model's extension to quasi-unilateral damage evolution is discussed. The crack progress in high-carbon steel sheet during blanking and the final sheared part morphology are predicted and compared with the experimental results. Sheared surface and burr height obtained by the analysis coincide with the results of the blanking experiment. 相似文献